Not for inexperienced Java Developers, but really the only decent JAX-WS book I could find. It covers most of the topic pretty well, but there are still some things you’ll need to find out yourself (most of which you can probably find in my tutorial). The chapter on his own framework can be missed out, but the rest is pretty good stuff.
I could write a review, but the reviews on Amazon say it all.
Read the Amazon reviews (and possibly even buy the book)!